Cerium isotope partition in the HCl/TBP extraction system |
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Authors: | W Dembiński K Goroncek |
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Institution: | (1) Department of Radiochemistry, Institute of Nuclear Chemistry and Technology, 03-195 Warsaw, Poland |
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Abstract: | The142/140Ce unit separation factor (q) for Ce(III)-Ce(IV) exchange reaction in an extraction system containing Ce(IV) in tri-n-butyl phosphate (TBP) and Ce(III) in hydrochloric acid has been determined. The value of q was found to be 0.9996±0.0001 (2) in the 12M HCl/TBP extraction system. The properties of the extraction systems containing nitric and hydrochloric acids in regard to isotope partition have been discussed. |
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