Investigation of peculiarities of the composition and structure of methylalumoxanes:27Al and1H NMR spectra of trimethylaluminum and products of its incomplete hydrolysis |
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| Authors: | N N Korneev I M Khrapova A V Polonskii N I Ivanova A V Kisin V S Kolesov |
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| Institution: | (1) State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123 Moscow, Russian Federation |
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| Abstract: | Trimethylaluminum and the methylalumoxanes produced by its incomplete (controlled) hydrolysis in various organic solvents have been investigated by27Al and1H NMR spectroscopy. Differences in the properties and spectral characteristics of methylalumoxanes obtained in toluene and pentane have been found.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1453–1457, August, 1993. |
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| Keywords: | trimethylaluminum hydrolysis methylalumoxanes structure |
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