Direct synthesis of radioactive carbon labeled fullerences using nuclear reactions |
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Authors: | K. Masumoto T. Ohtsuki K. Sueki K. Kikuchi T. Mitsugashira |
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Affiliation: | (1) Radiation Science Center, High Energy Accelerator Research Organization, 188 Tanashi, Tokyo, Japan;(2) Laboratory of Nuclear Science, Faculty of Science, Tohoku University, 982 Sendai, Miyagi, Japan;(3) Faculty of Science, Tokyo Metropolitan University, Hachioji, 192-03 Tokyo, Japan;(4) Institute for Materials Research, Tohoku University, Aoba, 980 Sendai, Japan |
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Abstract: | The11C and14C labeled fullerenes were produced by charged-particle and neutron irradiation, of C60, C70 and their mixture. It was found that a carbon atom of fullerence can be easily exchanged with a radioactive carbon atom produced by a nuclear reaction. The HPLC method was effective for identification and purification of various labeled fullerene families as chemically stable compounds. The radiochemically interesting aspect of the results is not only the production of11C and14C labeled fullerenes but also the formation of radioactive higher fullerenes which can be simultaneously produced with high yield and in carrier-free form. |
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