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Phase transition in triglycine family of hydrogen bonded ferroelectrics: An interpretation based on structural studies
Authors:R R Choudhury  R Chitra  P U Sastry  Amit Das  M Ramanadham
Institution:(1) Solid State Physics Division, Bhabha Atomic Research Centre, 400 085 Mumbai, India
Abstract:Using the crystal structure, a comprehensive interpretation of the origin of ferroelectricity in the hydrogen bonded triglycine family of crystals is given. Our detailed analysis showed that the instability of nitrogen double well potential plays a driving role in the mechanism of the ferroelectric transitions in these crystals.
Keywords:Triglycine sulphate  order-disorder  phase transitions  displacive
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