Diphenoxo-bridged Ni(II)Ln(III) dinuclear complexes as platforms for heterotrimetallic (Ln(III)Ni(II))2Ru(III) systems with a high-magnetic-moment ground state: synthesis, structure, and magnetic properties |
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Authors: | Palacios María A Mota Antonio J Ruiz José Hänninen Mikko M Sillanpää Reijo Colacio Enrique |
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Affiliation: | Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Avenida de Fuentenueva s/n, 18071 Granada, Spain. |
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Abstract: | The first examples of pentanuclear heterotrimetallic [(LnNi)(2)Ru] [Ln(3+) = Gd (1) and Dy (2)] complexes were prepared and magnetostructurally characterized. They exhibit ferromagnetic interactions, leading to a high-magnetic-moment ground state. |
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