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The instantaneous shear modulus in the shoving model
Authors:Dyre Jeppe C  Wang Wei Hua
Institution:DNRF Centre Glass and Time, IMFUFA, Department of Sciences, Roskilde University, Postbox 260, DK-4000 Roskilde, Denmark. dyre@ruc.dk
Abstract:We point out that the instantaneous shear modulus G(∞) of the shoving model for the non-Arrhenius temperature dependence of viscous liquids' relaxation time is the experimentally accessible high-frequency plateau modulus, not the idealized instantaneous affine shear modulus that cannot be measured. Data for a large selection of metallic glasses are compared to three different versions of the shoving model. The original shear-modulus based version shows a slight correlation to the Poisson ratio, which is eliminated by the energy-landscape formulation of the model in which the bulk modulus plays a minor role.
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