Abstract: | The title compound, a novel 30-membered 2:2 macrocyclic thiocarbohydrazone, C34H32N8O4S2·3C5H5N, has been prepared and crystallographically characterized. The molecule of the compound is twisted. One dioxabutane group is boat-like in shape, whereas the other is highly disordered. The crystal structure is stabilized by inter- and intramolecular hydrogen bonds. |