Tris{bis[N-(2-aminoethyl)-1,2-ethanediamine-κ3N]nickel(II)} bis(tetrathioantimonate) |
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Authors: | Ralph Stähler Christian Näther Wolfgang Bensch |
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Institution: | Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstraße 40, D-24089 Kiel, Germany |
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Abstract: | Yellow crystals of Ni(deta)2]3SbS4]2 (deta is diethylenetriamine, C4H13N3) were synthesized under solvothermal conditions by reacting elemental Ni, Sb and S in a solution of diethylenetriamine. The structure is composed of tetrahedral SbS4]3− anions in general positions and octahedral Ni(deta)2]2+ cations located at centres of inversion. In the crystal structure, the anions and cations are stacked in the direction of the a axis in a pseudo-hexagonal arrangement. |
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