3,6-Bis(dimethylamino)-10-propylacridinium iodide |
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Authors: | Raffaella Puliti Carlo Andrea Mattia |
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Abstract: | In the title compound, C20H26N3+·I−, the acridinium moiety shows mirror symmetry about the central C—N vector. The fused tricyclic system is only approximately planar and the geometry is affected by the presence of both dimethylamino groups and the propyl substitution at the central N atom. The propyl chain adopts an extended trans conformation and the plane through the chain C atoms is perpendicular to the mean plane through the rings. The I− ion is involved in short-range hydrogen-bonding interactions with two centrosymmetrically related cations via three activated acridinium C atoms. Stacks of acridinium cations propagate through the crystal along the c direction. The ring overlap is partial, but the dimethylamino groups also participate in the stacking. |
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