Study of rotations around C=C and C-N bonds in dienic δ- aminocarbonyl compounds by the NMR method |
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| Authors: | E P Prokof'ev Zh A Krasnaya V F Kucherov |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions We determined the free activation energies of the rotations around the C =C and C -N bonds in some unsaturated aminocarbonyl compounds and studied their dependence on the substituents, number of double bonds, solvent, and the concentration. Explanations of the observed processes were proposed on the basis of the obtained data.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2013–2022, September, 1973. |
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