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Organic radicals based on phenalenyl and verdazyl units |
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| Authors: | Yanhui Hou Huikai WangZhi Li Yongsheng LiuXiangjian Wan Xiaosong XueYongsheng Chen Ao Yu |
| Affiliation: | a School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300160, China b Key Laboratory for Functional Polymer Materials and Centre for Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China c Central Laboratory, College of Chemistry, Nankai University, Tianjin 300071, China |
| Abstract: | Stable phenalenyl (PLY) radicals without sterically bulky substituents need to be synthesized for application as neutral organic molecular conductors. Verdazyl radicals, which have high stability even without sterically bulky substituents, were combined with PLY radicals to produce two novel radicals. The stability of the dimethylthiourea substituted PLY radical is supported by the experimental results and quantum chemical calculations. |
| Keywords: | Radical Phenalenyl Verdazyl Crystal structure Spin density distribution |
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