Reactions of 2,2-dimethyl-3-phenylazirine with hydrazine and its derivatives |
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Authors: | A. V. Eremeev R. S. Él'kinson É. É. Liepin'sh |
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Affiliation: | (1) Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006 Riga |
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Abstract: | The corresponding -amino ketone hydrazones were obtained by reaction of 2,2-dimethyl-3-phenylazirine with hydrazine, N,N-dimethylhydrazine, methylhydrazine, and semicarbazide. It was established that unsymmetrical azines are formed in the reaction of 2-amino-2-methyl-1-phenyl-1-propanone hydrazone with aliphatic and cyclic ketones. The corresponding tetrahydro-1,2,4-triazines were obtained in the case of the analogous reaction with aliphatic and aromatic aldehydes.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 342–346, March, 1978. |
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