Structural features of the polymer-like phase of AC60 fullerides |
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Authors: | V. L. Aksenov V. S. Shakhmatov Yu. A. Osip’yan |
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Affiliation: | (1) Joint Institute of Nuclear Research, 141980 Dubna, Russia;(2) Instutute of Solid-State Physics, Russian Academy of Sciences, 142432 Chernogolovka, Russia |
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Abstract: | A new approach is proposed for describing the deformation of the C60 molecule in the polymer-like phase of the fullerides AC60 (A=K, Rb). A discrete basis of orientational states of the molecule is introduced, and orientational ordering is described on the basis of a phenomenological theory. A symmetry analysis of the molecular vibrations in the Fm3m phase is performed. It is shown that small rotations of the C60 can occur at a phase transition. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 2, 110–115 (25 July 1996) |
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