Structurally diverse Rh(I) and Mn(I) complexes derived from the new ambidentate indene ligand, (1-[iPr2P(S)]-2-[NMe2])C9H6 |
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| Authors: | Wechsler Dominik McDonald Robert Ferguson Michael J Stradiotto Mark |
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| Affiliation: | Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 4J3. |
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| Abstract: | A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a kappa2-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in kappa2-[C,S] and eta5 modes, respectively. |
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