| A Two-coordinate Copper(Ⅰ) Complex Constructed from Cyanuric Acid and 4,4′-Bipyridyl:Synthesis,Structure and Photoluminescence |
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| 作者姓名： | 岳琦 杨进 袁宏明 陈接胜 |
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| 作者单位： | State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry，Jilin University，Changchun，Jilin 130012，China，State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，College of Chemistry，Jilin University，Changchun，Jilin 130012，China，State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，College of Chemistry，Jilin University，Changchun，Jilin 130012，China，State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，College of Chemistry，Jilin University，Changchun，Jilin 130012，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(No.20331010). |
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| 摘 要： | A two-coordinate copper(Ⅰ)complex,Cu_2(bipy)(H_2L)_2(1)(H_3L=cyanuric acid,bipy=4,4'-bipyridyl),whichexhibits strong photoluminescence,has been synthesized under hydrothermal conditions and structurally character-ized by single crystal X-ray diffraction.The compound crystallizes in the monoclinic space group P2_1/n,with cellparameters:M_r=539.42,a=13.4806(5),b=4.5234(2),c=15.4952(8),β=105.526(3)°,V=910.39(7)~3,Z=2 and μ=3.52 mm~(-1).In the structure the two Cu(Ⅰ)ions are bridged by bipy to form a two-coordinate copper(Ⅰ)dimer.The adjacent dimer units are connected by hydrogen bonding interactions,resulting in 1D zigzag chainsalong the c axis.1 emits intense yellow light when excited with UV light.
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| 关 键 词： | copper(Ⅰ)complex photoluminescence cyanuric acid 4 4'-bipyridyl |
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