A Simple Indirect Route for the Synthesis of N-Alkyl-4-imino-1,4-dihydro-2H-3,1-benzoxazin-2-ones |
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| Authors: | Khosrow Jadidi Ramin Ghahremanzadeh Morteza Mehrdad Mohammad Ghanbari Hamid Arvin-Nezhad |
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| Affiliation: | (1) Department of Chemistry, Shahid Beheshti University, Tehran, Iran;(2) Department of Environmental Pollutants, Environmental Sciences Research Institute, Shahid Beheshti University, Tehran, Iran |
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| Abstract: | Summary. Novel N-alkyl-4-imino-1,4-dihydro-2H-3,1-benzoxazin-2-ones were synthesized in a single step by Baeyer–Villiger oxidation of N-alkyl-3-imino-2-indolinone derivatives in high yields. The structures of the products were determined by spectral data and by X-ray diffraction. Besides their novel structures, these compounds may have important biological activities and industrial applications. |
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| Keywords: | . 3,1-Benzoxazin-2-ones Baeyer– Villiger oxidation 3-Imino-2-indolinone. |
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