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A Simple Indirect Route for the Synthesis of N-Alkyl-4-imino-1,4-dihydro-2H-3,1-benzoxazin-2-ones
Authors:Khosrow Jadidi  Ramin Ghahremanzadeh  Morteza Mehrdad  Mohammad Ghanbari  Hamid Arvin-Nezhad
Institution:(1) Department of Chemistry, Shahid Beheshti University, Tehran, Iran;(2) Department of Environmental Pollutants, Environmental Sciences Research Institute, Shahid Beheshti University, Tehran, Iran
Abstract:Summary. Novel N-alkyl-4-imino-1,4-dihydro-2H-3,1-benzoxazin-2-ones were synthesized in a single step by BaeyerVilliger oxidation of N-alkyl-3-imino-2-indolinone derivatives in high yields. The structures of the products were determined by spectral data and by X-ray diffraction. Besides their novel structures, these compounds may have important biological activities and industrial applications.
Keywords:, 3,1-Benzoxazin-2-ones, Baeyer–,Villiger oxidation, 3-Imino-2-indolinone,
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