Positive ion pair cooperativity exhibited for the binding of phosphate under physiological conditions |
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| Authors: | Gunning Patrick T |
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| Affiliation: | University of Glasgow, Joseph Black Building, Dept. of Chemistry, Glasgow, UKG12 8QQ. patrick.gunning@yale.edu |
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| Abstract: | The synthesis of a heteroditopic receptor which exhibits positive cooperativity for the binding of phosphate ion pairs under physiological conditions. Optimised complementarity between crown ether host and metal guest leads to increased binding affinity, Ka. |
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