Blends of low-density polyethylene with nylon compatibilized with a sodium-neutralized carboxylate ionomer |
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Authors: | Atchara Lahor Brian P. Grady |
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Affiliation: | a The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330, Thailand b School of Chemical Engineering and Materials Science, University of Oklahoma, Norman, OK 73019, USA |
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Abstract: | An ethylene-methacrylic acid copolymer partially neutralized with sodium (Na-EMAA) was successfully used to compatibilize Nylon 6 (Ny6) and low-density polyethylene (LDPE) blends. The phase morphology and thermal behavior of these blends were investigated over a range of compositions using a variety of analytical techniques. The addition of small amounts (0.5 phr) of Na-EMAA improved the compatibility of Ny6/LDPE blends as evidenced by a significant reduction in dispersed phase sizes. TGA measurements demonstrated an improvement in thermal stability when Na-EMAA was added to either LDPE or Ny6. DSC results of Ny6/Na-EMAA binary blends showed that with increasing Na-EMAA content, the crystallization temperature of Ny6 phase decreased indicating that Na-EMAA retarded crystallization of Ny6. TGA and DSC results indicate that chemical reactions might have taken place between Ny6 and Na-EMAA, a hypothesis confirmed by the Molau test. |
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Keywords: | Sodium-neutralized carboxylate Ionomers blend Compatibilizer Low-density polyethylene Nylon 6 |
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