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The preparation of a new polysiloxane copolymer with glucosylthioureylene groups on the side chains
Authors:Chuan Jian Zhou  Sheng Yu Feng
Affiliation:a School of Chemistry and Chemical engineering, Shandong University, Ji’nan, Shandong 250100, PR China
b School of Materials Science and Engineering, Ji Nan University, Ji’nan, Shandaon 250022, PR China
Abstract:A new polysiloxane with pendent sugar units was prepared by a two-step method: the preparation of the polysiloxane with amino groups on the side chain and then the copolysiloxane reacted with glucosyl isothiocyanate. All polymers were characterized by FT-IR 1H-NMR, 1H-1H-COSY, 13C-NMR, and DEPT respectively. In the same time, Platinum oxide was found to be a versatile and powerful hydrosilation catalyst in the hydrosilylation reaction of aminotrimethylenepolysiloxanes with heptamethylcyclotetrasiloxane (D4H).
Keywords:Saccharide   Polysiloxane   Platinum oxide   Hydrosilylation   Aminotrimethylenepolysiloxanes
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