The preparation of a new polysiloxane copolymer with glucosylthioureylene groups on the side chains |
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Authors: | Chuan Jian Zhou Sheng Yu Feng |
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Affiliation: | a School of Chemistry and Chemical engineering, Shandong University, Ji’nan, Shandong 250100, PR China b School of Materials Science and Engineering, Ji Nan University, Ji’nan, Shandaon 250022, PR China |
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Abstract: | A new polysiloxane with pendent sugar units was prepared by a two-step method: the preparation of the polysiloxane with amino groups on the side chain and then the copolysiloxane reacted with glucosyl isothiocyanate. All polymers were characterized by FT-IR 1H-NMR, 1H-1H-COSY, 13C-NMR, and DEPT respectively. In the same time, Platinum oxide was found to be a versatile and powerful hydrosilation catalyst in the hydrosilylation reaction of aminotrimethylenepolysiloxanes with heptamethylcyclotetrasiloxane (D4H). |
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Keywords: | Saccharide Polysiloxane Platinum oxide Hydrosilylation Aminotrimethylenepolysiloxanes |
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