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SBR-XNBR blends: a novel approach towards compatibilization
Authors:T Biswas  SC Debnath  AR Das
Institution:a Department of Plastics Engineering, G.B. Pant Polytechnic, Okhla, New Delhi 1000220, India
b Polymer Science Unit, Indian Association for the Cultivation of Science, Jadavpur, Calcutta 700 032, India
Abstract:The role of a few ionic and non-ionic surfactants on the solubilization of polar carboxylated nitrile rubber and non-polar styrene butadiene rubber as interfacial compatibilizer has been investigated. Conspicuous changes of characteristic features of the blend vulcanizates e.g. modulus at 200% elongation, tensile strength, elongation at break, hardness, age resistance etc are observed. The cationic surfactant, tetra butyl ammonium bromide and the anionic sodium dodecyl sulfate are found to inhibit the physical properties while the non-ionics favor the phenomenon. Scanning electron microscope supports the observed behavior.
Keywords:Surfactants  Bis(diisopropyl) thiophosphoryl disulfide  Styrene butadiene rubber-carboxylated nitrile rubber blend  Compatibilization
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