Phase equilibria in quasi-binary sections of the Tl-Sn-S system |
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Authors: | T A Malakhovskaya-Rosokha M Yu Sabov I E Barchii E Yu Peresh |
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Institution: | 1.Institute of Solid-State Physics and Chemistry,Uzhgorod,Ukraine;2.Chair of Inorganic Chemistry,Uzhgorod National University,Uzhgorod,Ukraine |
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Abstract: | Phase equilibria in quasi-binary sections of the Tl-Sn-S system: (I) Tl4SnS4-SnS, (II) Tl2SnS3-SnS, (III) S-Tl4SnS4, (IV) S-Tl2SnS3, (V) Tl-SnS, and (VI) Tl2S-SnS were studied by differential thermal analysis and X-ray powder diffraction. It was found that systems I and II are characterized
by the eutectic type of interaction, the phase diagrams of systems III and IV are of the eutectic type with a degenerate eutectic
at the sulfur melting point, and the phase diagram of system V is of the fourth type according to Roozeboom. Phase equilibria
in system VI were specified. |
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