Ruthenium clusters containing the [2.2] paracyclophane ligand: Recent developments in arene-cluster chemistry |
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Authors: | Paul J. Dyson Brian F. G. Johnson Caroline M. Martin |
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Affiliation: | (1) Department of Chemistry, The University of Edinburgh, West Mains Road, EH9 3JJ Edinburgh, UK |
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Abstract: | In this article we review the synthesis, reactivity, and characterization of a number of clusters bearing the [2.2] paracyclophane ligand with nuclearities ranging from two to eight. Particular attention is focused on the different coordination modes that paracyclophane adopts; these being µ1-6, µ2-3 :3, µ3-1 :2 :2, and µ3-2 :2 :2. Structural modifications which take place within the ring system on bonding in these various modes are also discussed. |
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Keywords: | Cluster paracyclophane carbonyl ruthenium |
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