Reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen in the presence of metal compounds |
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| Authors: | V B Vol'eva E V Ivanov I A Batanov V V Ershov |
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| Institution: | (1) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions A dependence was found for the isomer composition of the quinolide peroxides formed upon the oxidation of 2,4,6-tri-tert-butylphenol on the coordination capacity of the metal compounds used for the oxidation and the medium. Kinetic measurements showed that the reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen is accelerated in the presence of manganese diacetate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 706–709, March, 1986. |
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