Pd/C-catalyzed Reductive Mono-N-alkylation of Nitrophenol Derivatives in One-pot Way |
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| Authors: | JIN Zhonghao LI Dao WANG Xingyi LU Guanzhong |
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| Institution: | 1. Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China;2. Tel./Fax: 0086‐021‐64253372 |
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| Abstract: | A range of different nitrophenol derivatives were converted in one‐pot to the corresponding secondary alkyl aminophenols in good to excellent yields by using ketones as alkyl source and hydrogen over 10 wt% Pd/C as reducing agent. In all examples, except for one, the secondary amine was the sole alkylation product isolated. When aldehydes were used as alkyl source, the corresponding tertiary amine as a sole alkylation product was isolated. |
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| Keywords: | one‐pot reductive mono‐N‐alkylation nitrophenol secondary alkyl aminophenol Pd/C |
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