| 硫代四配位磷化物与邻苯二酚反应 |
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| 引用本文： | 刘纶祖,曹如珍,蔡宝忠,杨小蕙.硫代四配位磷化物与邻苯二酚反应[J].高等学校化学学报,1988,9(7):737. |
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| 作者姓名： | 刘纶祖 曹如珍 蔡宝忠 杨小蕙 |
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| 作者单位： | 南开大学元素有机化学研究所 |
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| 摘 要： | 前文报1]道的硫代磷酰二氯在三乙胺存在下与邻苯二酚反应,不仅具有理论意义,而且是合成该类磷化物的新方法。本文将继续报道硫代磷酰一氯以及其它硫代四配位磷化物与邻苯二酚反应的结果,以期进一步揭示这类反应的本质及其影响因素。
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| 关 键 词： | 五配位磷 六配位磷 硫代磷酸酯 |
| 收稿时间： | 1987-02-13 |
The Reaction of Tetracoordinated Thiophosphoryl Compounds with Catechol |
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| Liu Lunzu,Cao Ruzhen,Gai Baozhong,Yang Xiaohui.The Reaction of Tetracoordinated Thiophosphoryl Compounds with Catechol[J].Chemical Research In Chinese Universities,1988,9(7):737. |
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| Authors: | Liu Lunzu Cao Ruzhen Gai Baozhong Yang Xiaohui |
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| Institution: | Institute of Elemento-Organic Chernistry, Nankai University, Tianjin |
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| Abstract: | The reaction of a series of phosphorochloridothioates with catechol in the presence of triethylamine yields a hexacoordinated phosphorus, compound Ⅱ. Phenyl thiophosphonyl chlorides reacted with catechol to produce a pentacoordina-ted phosphorus compound Ⅴ. Phenyl. pyrophosphonothioate reacts with catechol to give Ⅱ and Ⅴ. The mechanism of these reaction were discussed, too. |
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| Keywords: | Phosphoranes Phosphorates Thiophosphates |
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