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Synthesis and Structure of 1- and 2-Isomers of (Trimethoxysilylmethyl) and (Silatranylmethyl)benzotriazole
Authors:M. G. Voronkov  O. M. Trofimova  Yu. I. Bolgova  L. V. Klyba  L. I. Larina  A. I. Albanov  V. A. Pestunovich  N. F. Chernov  K. B. Petrushenko
Affiliation:(1) Siberian Branch, Russian Academy of Sciences, A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk, 664033
Abstract:We have synthesized 1- and 2-(trimethylsilylmethyl)- and 1- and 2-(trimethoxysilylmethyl)benzotriazoles by reaction of 1,2,3-benzotriazolylsodium with trimethyl- or trimethoxy(chloromethyl)silane. We obtained 1- and 2-(silatranylmethyl)benzotriazoles by transesterification of the latter with triethanolamine.
Keywords:1- and 2-silatranylmethylbenzotriazole  1- and 2-trimethoxysilylmethylbenzotriazole
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