Two-dimensional crystallization: self-assembly, pseudopolymorphism, and symmetry-independent molecules |
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Authors: | Plass Katherine E Kim Kibum Matzger Adam J |
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Institution: | Department of Chemistry and the Macromolecular Science and Engineering Program, The University of Michigan, Ann Arbor, Michigan 48109-1055, USA. |
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Abstract: | The self-assembly of a series of 1,3-disubstituted benzenes has been scrutinized by scanning tunneling microscopy (STM) and computational modeling. Small changes in the functional groups (e.g., ester, thioester, ketone) resulted in dramatic changes in packing patterns. Remarkably, several of the molecules gave rise to monolayers with more than one molecule in the asymmetric unit and displayed multiple packing patterns. This constitutes the most complex behavior observed to date in this type of monolayer and illuminates several issues of importance in three-dimensional crystallization. Intermolecular interactions associated with the observation of multiple molecules in the asymmetric unit and stabilization of pseudopolymorphs were identified. The geometry and electrostatic properties of the isolated molecule and monolayer density were found to be critical in determining which packing motif was adopted. |
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