On Evaluation of Overlap Integrals with Noninteger Principal Quantum Numbers |
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Authors: | II Guseinov and BA Mamedov |
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Institution: | 1. Department of Physics, Faculty of Arts and Sciences, Onsekiz Mart University, Canakkale, Turkey
;2. Department of Physics, Faculty of Arts and Sciences,
Gaziosmanpasa University, Tokat, Turkey |
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Abstract: | By use of complete orthonormal sets of ψα exponential-type
orbitals (ψα-ETOs, α= 1,0,
-1, -2, …) the series
expansion formulas for the noninteger n* Slater-type orbitals (NISTOs)
in terms of integer n Slater-type orbitals (ISTOs) are derived. These
formulas enable us to express the overlap integrals with NISTOs through the
overlap integrals over ISTOs with the same and different screening
constants. By calculating concrete cases the convergence of the series for
arbitrary values of noninteger principal quantum numbers and screening
constants of NISTOs and internuclear distances is tested. The accuracy of
the results is quite high for quantum numbers, screening constants and
location of STOs. |
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Keywords: | Slater-type orbitals exponential-type orbitals noninteger principal quantum numbers overlap integrals |
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