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Synthesis of selenylfullerene with selenium-containing dibenzo[b,g]cyclooctane moiety |
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| Authors: | Tsukasa Nakahodo Midori O Ishitsuka Yutaka Maeda Hisashi Fujihara Takeshi Akasaka |
| Institution: | a Department of Applied Chemistry, Kinki University, Kowakae, Higashi-Osaka 577-8502, Japan b Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan c Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan d PRESTO, Japan Science and Technology Agency, Tokyo 102-0075, Japan e Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan |
| Abstract: | The photochemical reaction of C60 with selenium-containing bicyclooctanes affords for the first time the selenylfullerenes. The derivatives were characterized by mass, UV-vis absorption, NMR spectroscopy, and X-ray crystallographic analysis. |
| Keywords: | Selenylfullerene Chalcogen Dibenzocyclooctane Photochemical reaction C60 |
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