Lobozoanthamine, a new zoanthamine-type alkaloid from the Indonesian soft coral Lobophytum sp. |
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Authors: | Ernesto Fattorusso Orazio Taglialatela-Scafati M. Janib Achmad Carlo Cerrano |
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Affiliation: | a Dipartimento di Chimica delle Sostanze Naturali, Università di Napoli ‘Federico II’, Via D. Montesano 49, 80131 Napoli, Italy b Faculty of Fisheries and Marine Sciences, Sam Ratulangi University, 95115 Manado, Indonesia c Dipartimento di Scienze del Mare, Università Politecnica delle Marche, Via Brecce Bianche, 60131 Ancona, Italy d Dipartimento per lo Studio del Territorio e delle sue Risorse, Università di Genova, Corso Europa 26, 16132 Genova, Italy |
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Abstract: | A new member of the family of zoanthamine-type alkaloids, lobozoanthamine (1), has been isolated from the Indonesian soft coral Lobophytum sp. This represents the first report of a zoanthamine-type alkaloid from a marine invertebrate different from zoanthids. The densely functionalized heptacyclic stereostructure of lobozoanthamine (1) has been established through the interpretation of 2D NMR data and application of the modified Mosher method. |
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Keywords: | Lobophytum sp. Indonesia Zoanthamine Alkaloids Structure elucidation NMR |
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