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Functionalized 3,4-ethylenedithiathiophenes (EDTTs) as building blocks for poly (3,4-ethylenedithiathiophene) (PEDTT) derivatives
Authors:Raúl Blanco
Institution:Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, E-28040 Madrid, Spain
Abstract:A convenient and straightforward procedure has been developed for the preparation of functionalized 3,4-ethylenedithiathiophene (EDTT) derivatives by using a new bromomethyl-EDTT derivative as a versatile synthon. Based on this procedure a novel EDTT derivative endowed with 9,10-anthraquinone moieties has been synthesized and electrochemically polymerized to yield a donor-acceptor PEDTT derivative.
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