Construction of the adamantane core of plukenetione-type polycyclic polyprenylated acylphloroglucinols |
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| Authors: | Takagi Ryukichi Inoue Yuta Ohkata Katsuo |
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| Institution: | Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan. rtakagi@hiroshima-u.ac.jp |
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| Abstract: | The construction of a highly functionalized adamantane core of plukenetione-type polycyclic polyprenylated acylphloroglucinols (PPAPs) is described. The method features the construction of the bicyclo3.3.1]nonane core (3) by successive Michael reactions and the construction of the adamantane core of plukenetione-type PPAPs by acid-catalyzed cyclization of a bicyclo3.3.1]nonane precursor (2). |
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