Convenient access to bicyclic and tricyclic diazenes |
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| Authors: | Taber Douglass F Guo Pengfei |
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| Affiliation: | Department of Chemistry, University of Delaware, Newark, Delaware 19716, USA. taberdf@udel.edu |
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| Abstract: | Heating the tosylhydrazone of an omega-alkenyl ketone or aldehyde to reflux in toluene in the presence of K(2)CO(3) delivered the bicyclic diazene. Irradiation of the diazene converted it to the cyclopropane. This appears to be a generally useful method for the construction of substituted cyclopentanes and cyclohexanes. |
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