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胶束催化体系中的对映选择性环醚化反应
引用本文:Bhupesh S. SAMANT,Sunil S. BHAGWAT. 胶束催化体系中的对映选择性环醚化反应[J]. 催化学报, 2011, 32(2): 231-234. DOI: 10.1016/S1872-2067(10)60169-6
作者姓名:Bhupesh S. SAMANT  Sunil S. BHAGWAT
作者单位:Natural Product and Medicinal Chemistry Research Group;Division of Pharmaceutical chemistry;Faculty of Pharmacy;Rhodes University Grahamstown;Department of Chemical Engineering;Institute of Chemical Technology;
基金项目:Supported by the Rhodes University Joint Research Committee (JRC,grant number 35047)
摘    要:

关 键 词:醚化反应  催化体系  对映选择性  胶束  

Enantioselective Cycloetherification in a Micellar Catalysis System
Bhupesh S. SAMANT,Sunil S. BHAGWAT. Enantioselective Cycloetherification in a Micellar Catalysis System[J]. Chinese Journal of Catalysis, 2011, 32(2): 231-234. DOI: 10.1016/S1872-2067(10)60169-6
Authors:Bhupesh S. SAMANT  Sunil S. BHAGWAT
Affiliation:Bhupesh S. SAMANT1,Sunil S. BHAGWAT2 1Natural Product and Medicinal Chemistry Research Group,Division of Pharmaceutical chemistry,Faculty of Pharmacy,Rhodes University,Grahamstown,6140,South Africa 2Department of Chemical Engineering,Institute of Chemical Technology,Matunga,Mumbai,400 019,India
Abstract:The enantioselective cycloetherification of substituted keto phenols into their corresponding dihydrobenzofuran derivatives was carried out using hydrogen peroxide and chiral quaternary ammonium iodide in micellar media. This approach increased the conversion rate of cycloetherification and also widened the scope of this particular reaction for various substituted keto phenols with electron withdrawing as well as electron donating functionalities. The use of a surfactant in the cycloetherification reaction ...
Keywords:enantioselective cycloetherification  dihydrobenzofuran derivative  micellar catalysis  
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