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原油中含氧化合物的质谱分析
引用本文:陈茂齐,刘有邦,张世英. 原油中含氧化合物的质谱分析[J]. 分析测试学报, 1992, 0(2)
作者姓名:陈茂齐  刘有邦  张世英
作者单位:中国科学院兰州化学物理研究所(陈茂齐,刘有邦),中国科学院兰州化学物理研究所(张世英)
摘    要:本文介绍自原油分离含氧化合物,酯化混合酸和用毛细管气相色谱-质谱(GC-MS)鉴定其组分的方法。色谱-质谱分离并鉴定出C_8—C_(30)的脂肪酸、分子量为484和498的二对藿烷酸的立体异构体,烷基酚,邻苯二甲酸酯等,并首次发现石油中含有癸二酸二异辛酯类组分。

关 键 词:色谱-质谱分析  原油  含氧化合物

Analysis of Oxygen-Containing Compounds by Mass Spectrometry in Crude Oil
Chen Maoqi,Liu Youbang,Zhang ShiyingLanzhou Institue of Chemical Physics,Chinese Academy of Seiences. Analysis of Oxygen-Containing Compounds by Mass Spectrometry in Crude Oil[J]. Journal of Instrumental Analysis, 1992, 0(2)
Authors:Chen Maoqi  Liu Youbang  Zhang ShiyingLanzhou Institue of Chemical Physics  Chinese Academy of Seiences
Abstract:In crude oil from Henan province, five groups of oxygen-containing compound are identifiedby capillary gas chromatography-mass spectrometer. They are fatty acids of 8-30 carbon atomshaving a molecular weight between 484 and 498; polycylic-acids of hopanoic series:phthalates;alkylphenols; and diisooctyl esters of decanedioic acid. Their quantitative determination can alsobe achieve by this method.
Keywords:GC-MC  Crude Oil  Oxygen-Containing compound  
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