A diatropic ring current in a fluorofullerene trannulene |
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| Authors: | Burley Glenn A Fowler Patrick W Soncini Alessandro Sandall John P B Taylor Roger |
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| Institution: | University of Sussex, School of Chemistry, Physics & Environmental Science, Brighton, UK BN1 9Q. |
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| Abstract: | Ipsocentric current-density maps for a fluorofullerene derivative, C60F15H3, modelling the addition pattern of the experimentally characterised C60F15CBr(CO2Et)2]3 which contains an 18]trans-annulene system, reveal a diamagnetic ring current dominated by the contribution of the four HOMO electrons, as in a classical (4n + 2) aromatic annulene. |
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