首页 | 本学科首页   官方微博 | 高级检索  
     


Exohedral multiple bonding in polyhedra. 2. Skeletal distortions in ring-stacked boranes
Authors:Balakrishnarajan Musiri M  Hoffmann Roald
Affiliation:Department of Chemistry and Biochemistry, Cornell University, Ithaca, New York 14853, USA.
Abstract:Ring-stacked boranes of the B(10)H(10)(2)(-) and B(12)H(12)(2)(-) type, when substituted with lone pair bearing groups such as -O, -NH, and -S at the para positions, are theoretically shown to exhibit exopolyhedral multiple bonding on oxidation. Successive removal of two and four electrons from the parent B(n)H(n)(-)(2)X(2) results in highly varied and intriguing skeletal deformations that are explained using fragment molecular theory.
Keywords:
本文献已被 PubMed 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号