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Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films |
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| Authors: | Grumelli Doris E Wolosiuk Alejandro Forzani Erica Planes Gabriel A Barbero César Calvo Ernesto J |
| Affiliation: | INQUIMAE-Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, AR-1428 Buenos Aires, Argentina. |
| Abstract: | Probe beam deflection during chronoamperometric oxidation-reduction of osmium complex in layer-by-layer self-assembled redox active polyelectrolyte multilayers has shown that the nature of the charge in the topmost layer determines the ion flux that balances the redox charge. |
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