A Novel Heterometallic Cluster-Based Coordinational Polymer with 2-[Bis-(2-hydroxy-ethyl)-Amino]-Ethanesulfonic Acid: Synthesis and Crystal Structure |
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| Authors: | Chun Lian Zhang Xi Fu Jiang Li Yang Shu Hua Zhang Shao Ming Shi |
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| Institution: | 1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, People’s Republic of China
2. Liu Zhou Vocation & Technical College, Liuzhou, 545006, Guangxi, People’s Republic of China
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| Abstract: | A rare heterometallic cluster-based polymer Cu4(Hbhea)4(μ 2-OCH3) K(CH3OH))] n ·(H2O) n (1) (H3bhea = 2-bis-(2-hydroxy-ethyl)-amino]-ethanesulfonic acid), has been synthesized and structurally determined by single crystal X-ray diffraction, elemental analysis. Crystallographic unit of 1 consists of four Cu(II), four Hbhea ligands, one methanol molecule, one methanol anion, one K ion and one crystal lattice water and formed anion cluster Cu4(Hbhea)4(CH3O)]? which further constructed a 3-D polymer by linking the six-coordination K ions. |
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