Phototransformations of 6-X-5-Nitroquinoxalines |
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Authors: | Rtishchev N. I. Selitrennikov A. V. |
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Affiliation: | (1) St. Petersburg State Institute of Technology, St. Petersburg, Russia |
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Abstract: | Photophysical properties and photochemical activity of 6-X-5-nitroquinoxalines with electron-donor substituents (X = H, CH3, Cl, OC2H5, NH2) ortho to the nitro group were studied. The quantum yield of the formation of 5-hydroxyquinoxaline from the corresponding nitro derivative depends on the nature of the substituent and irradiation conditions. Phototransformations can go through nitro-nitrite rearrangement with the participation of two alternative T(n*) levels, depending on the size and electronic effects of the substituent. The latter factor is largely determined by the population on excitation of different charge-transfer states involving the nitro group. |
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