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Electron ionization-induced fragmentation of some new dibenzo(d, f)(1,3)dioxepine derivatives
Authors:Begala Michela  Tocco Graziella  Delogu Giovanna  Meli Gabriele  Picciau Carmen  Podda Gianni
Affiliation:Dipartimento Farmaco Chimico Tecnologico, Università di Cagliari, Via Ospedale 72, 09124 Cagliari, Italy. michelabegala@yahoo.it
Abstract:The mass spectrometric behaviour of a series of 6,6-disubstituted dibenzo(d,f)(1,3)dioxepine derivatives have been studied. The fragmentation patterns were described and discussed in detail with the aid of labelled compounds, accurate mass measurements and collisionally induced dissociation experiments performed using an ion trap.
Keywords:electron ionization mass spectra  multiple‐stage experiments  mechanisms  dibenzo(d, f)(1,3)dioxepine derivatives
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