| The synthesis and crystal structure of heteronuclear complex of lanthanide with sulfo-salicylic acid [Na3YLa2(C7H3SO6)4.26H2O]n |
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| 作者姓名： | SUN Hong-Ye HUANG Chun-Hui GAN Liang-Bing XU Guang-XianState Key Laboratory of Rare Earth Material Chemistry and Applications Peking University Beijing ChinaMA Zhe-Sheng SHI Ni-Cheng China University of Geoscience Beijing China |
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| 作者单位： | SUN，Hong-Ye HUANG，Chun-Hui GAN，Liang-Bing XU，Guang-XianState Key Laboratory of Rare Earth Material Chemistry and Applications，Peking University，Beijing 100871，ChinaMA，Zhe-Sheng SHI，Ni-Cheng China University of Geoscience，Beijing 100083，China |
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| 基金项目： | supported by the National Natural Science Foundation of China and Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences. |
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| 摘 要： | The titled complex has been synthesized by the reaction of sodium sulfo-salicylate with lanthanum and yttrium perchlorate. The crystal structure has been determined by single crystal X-ray diffractometry. The crystal is monoclinic with space group C2/c. The unit cell parameters are as follows: a=16.289(8), b=18.323(8), c=22.044(8) A, β=106.34(2)°, V=6314(6) A3, Z=4 and Dc=1.764 g/cm3. The structure was solved by direct method. The least-square refinement based on 3776 observed reflections F > 6σ(F)] converged to a final R=8.6% and F(000) is 3548. Yttrium ion with eight-coordinate is located in central of the molecule, the two lanthanum ions with ten-coordinate are located at the two sides of yttrium ion. There are two positions for Na in the molecule, one is in the C2 axis with six coordinate, the other one is in a general position with five-coordinate.
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The synthesis and crystal structure of heteronuclear complex of lanthanide with sulfo-salicylic acid [Na3YLa2(C7H3SO6)4.26H2O]n |
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| SUN,Hong-Ye HUANG,Chun-Hui GAN,Liang-Bing XU,Guang-XianState Key Laboratory of Rare Earth Material Chemistry and Applications,Peking University,Beijing ,ChinaMA,Zhe-Sheng SHI,Ni-Cheng China University of Geoscience,Beijing ,China.The synthesis and crystal structure of heteronuclear complex of lanthanide with sulfo-salicylic acid [Na3YLa2(C7H3SO6)4.26H2O]n[J].Chinese Journal of Chemistry,1995,13(2):150-155. |
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| Authors: | SUN Hong-Ye HUANG Chun-Hui GAN Liang-Bing XU Guang-XianState Key Laboratory of Rare Earth Material Chemistry and Applications Peking University Beijing ChinaMA Zhe-Sheng SHI Ni-Cheng China University of Geoscience Beijing China |
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| Institution: | SUN,Hong-Ye HUANG,Chun-Hui GAN,Liang-Bing XU,Guang-XianState Key Laboratory of Rare Earth Material Chemistry and Applications,Peking University,Beijing 100871,ChinaMA,Zhe-Sheng SHI,Ni-Cheng China University of Geoscience,Beijing 100083,China |
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| Abstract: | The titled complex has been synthesized by the reaction of sodium sulfo-salicylate with lanthanum and yttrium perchlorate. The crystal structure has been determined by single crystal X-ray diffractometry. The crystal is monoclinic with space group C2/c. The unit cell parameters are as follows: a=16.289(8), b=18.323(8), c=22.044(8) Å, β=106.34(2)°, V=6314(6) Å3, Z=4 and Dc= 1.764 g/cm3. The structure was solved by direct method. The least-square refinement based on 3776 observed reflections F > 6σ(F)] converged to a final R=8.6% and F(000) is 3548. Yttrium ion with eight-coordinate is located in central of the molecule, the two lanthanum ions with ten-coordinate are located at the two sides of yttrium ion. There are two positions for Na in the molecule, one is in the C2 axis with six coordinate, the other one is in a general position with five-coordinate. |
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| Keywords: | Crystal structure heteronucleax complex lanthanide elements sulfo-salicylic acid |
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