Charge transfer and tunable ambipolar effect induced by assembly of Cu(II) binuclear complexes on carbon nanotube field effect transistor devices |
| |
Authors: | Magadur Gurvan Lauret Jean-Sébastien Charron Gaëlle Bouanis Fatima Norman Evgeny Huc Vincent Cojocaru Costel-Sorin Gómez-Coca Silvia Ruiz Eliseo Mallah Talal |
| |
Institution: | Institut de Chimie Moléculaire et des Matériaux d'Orsay, Université de Paris Sud 11, CNRS, Bat. 420, 15 rue Georges Clemenceau, 91405 Orsay Cedex, France. gurvan.magadur@u-psud.fr |
| |
Abstract: | Assembly of paramagnetic Cu(2) complexes with a Schiff base scaffold possessing extended electron delocalization together with a quasi-planar structure onto carbon nanotubes induces a diameter-selective charge transfer from the complex to the nanotubes leading to an interestingly large and tunable ambipolar effect. We used complementary techniques such as electron paramagnetic resonance, absorption spectroscopy, and photoluminescence to ensure the success of the assembly process and the integrity of the complex in the nanohybrid. We carried out density functional theory type calculations to rationalize the experimental results, evidencing the selective enhanced interaction of the metal complexes with one type of nanotube. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|