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The synthesis of ferrocenyl- and ferrocenoylpyrimidines |
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| Authors: | K. Ya. Zherebker A. N. Rodionov E. S. Pilipenko V. V. Kachala O. M. Nikitin Yu. A. Belousov A. A. Simenel |
| Affiliation: | 1. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia 2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia 3. Lomonosov Moscow State University, Moscow, Russia 4. Moscow State Mining University, Moscow, Russia |
| Abstract: | New derivatives of pyrimidine were synthesized from ferrocenyl ketones by the reactions of [3+1+1+1]annulation and intermolecular cyclization. The electrochemical behavior of the obtained compounds was studied by the method of cyclic voltammetry. All the compounds may be characterized with the signal, corresponding to the reversible one-electron transfer in ferrocene-ferrecinium and lowering of the redox potential with respect to ferrocene. |
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