Low temperature isomerization of n-hexane on catalyst systems Al2O3/ZrO2/SO4/Pt |
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Authors: | E V Chuparev P A Zernov O I Parputs N V Lisitsyn |
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Institution: | 1. St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia 2. JSC “RRT Ltd.”, ul. Serpukhovskaya 10, St. Petersburg, 190013, Russia
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Abstract: | As a result of investigating low temperature isomerization of n-hexane at 130, 140, 150, 160°C in a flow reactor with a fixed bed of catalyst of the Al2O3/ZrO2/SO4/Pt type a ratio of components in the catalyst system was selected and process conditions were defined, which allow to obtain highly branched high-octane isomers with a yield of up to 40% relative to a transformed raw material. A kinetic model of the process was proposed and kinetic parameters were calculated. |
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