NiII(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA |
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| Authors: | Nagataki Takayuki Tachi Yoshimitsu Itoh Shinobu |
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| Institution: | Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan. |
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| Abstract: | A simple Ni(II)(TPA) complex TPA = tris(2-pyridylmethyl)amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO(+) (nickel-oxo) type active oxygen species is suggested. |
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