Total synthesis of capsanthin and capsorubin using Lewis acid-promoted regio- and stereoselective rearrangement of tetrasubsutituted epoxides |
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| Authors: | Yamano Yumiko Ito Masayoshi |
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| Affiliation: | Kobe Pharmaceutical University, Motoyamakita-Machi, Kobe, Japan. y-yamano@kobepharma-u.ac.jp |
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| Abstract: | The synthesis of capsanthin 1 and capsorubin 2 was accomplished via the C(15)-cyclopentyl ketone 6 prepared by Lewis acid-promoted regio- and stereoselective rearrangement of the epoxy dienal 5. |
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