Use of gamma-carboxy-alpha,beta-unsaturated aldehydes as synthetic equivalents of beta,gamma-unsaturated aldehydes in a novel stereoselective approach to diketides |
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| Authors: | Hughes Lautens Wen |
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| Affiliation: | Department of Chemistry, University of Toronto, Ontario, Canada. |
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| Abstract: | [reactions: see text] A two-step aldol/Pd-catalyzed formate reduction sequence allows for convenient, stereoselective access to products of great potential in synthetic approaches to polyketides. A novel diastereoselective Pd-catalyzed formate reduction of allylic acetates is reported. |
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