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Formation of organomagnesium compounds via EtMgBr-mediated radical cyclization of allyl beta-iodoacetals
Authors:Inoue  Shinokubo  Oshima
Institution:Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan.
Abstract:reaction: see text] Treatment of allyl beta-iodoacetals with ethylmagnesium bromide in THF provided tetrahydrofuran derivatives in good yields. On the other hand, the reaction in DME provided tetrahydrofuranylmethylmagnesium compounds in good yields.
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