Formation of organomagnesium compounds via EtMgBr-mediated radical cyclization of allyl beta-iodoacetals |
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Authors: | Inoue Shinokubo Oshima |
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Institution: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan. |
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Abstract: | reaction: see text] Treatment of allyl beta-iodoacetals with ethylmagnesium bromide in THF provided tetrahydrofuran derivatives in good yields. On the other hand, the reaction in DME provided tetrahydrofuranylmethylmagnesium compounds in good yields. |
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